How to Farm Titanium - Outriders Wiki Guide - IGN

The most important thing to note about farming Titanium is that you won't be able to effectively acquire lots of Titanium until you are high enough level to reach higher World Tier levels, which give you better rewards for increased difficulty.

It's not the most cost-effective method when you first unlock her shop, but once you hit World Tier 8 or 9 and start receiving more Epic items, you can start selling all your Unusual or Rare gear to exchange for Titanium.

Upgrading a piece of Lv 30 gear from Rare to Epic costs 50 Titanium, which you can purchase from Bailey for ≈16K scrap.

Though you won't want to do this to the first few pieces of Epic or Legendary gear you find, once you hit endgame, you shouldn't get too attached to subpar epic or better gear that can be disassembled to get Titanium needed to upgrade the items you really care about